The Basel Problem
The Basel problem asks for the exact sum of the reciprocals of the squares.
$$\sum_{n=1}^{\infty} \frac{1}{n^2} = \frac{\pi^2}{6}$$
Why It Is Surprising
The left side is a sum of rational numbers. The right side involves $\pi$, a geometric constant. There is no obvious reason they should be equal.
Euler solved this in 1734 at age 28 by noticing a connection between the sine function and infinite products. It made him famous.